Skilled in Business Planning, Operations Management, Business Intelligence, and Logistics Management. Natl Acad. b, Estimated change in e65 in 2020 based on the difference from life tables calculated for 2019 and 2020 by state and sex. <> In both cases, the nonamers were solvated in a 3:1 butanol/water mixture to mimic the most challenging esterification conditions. Given a growing emphasis on sustainability within the polymer industry, including calls to increase the circularity of polymer production12, this LCA provides an important metric for evaluating approaches to polymer recycling. Sonicating 2.5% and 5.0% w/v solutions of decrosslinked PAAP&G for 010min using a 20kHz sonication horn operating at full amplitude (100%) revealed rapid chain-shortening for the decrosslinked PAAP&G (Fig. We calculated nRx, the age-specific and sex-specific ratio of deaths from all causes other than COVID-19 to deaths inclusive of COVID-19. The impact of COVID-19 on people with diabetes in Brazil. (ed.) Takaya, C. A. et al. The estimated decline for Brazil was 0.94 years for both sexes, 0.66 years for females and 1.17 years for males. Under ultrasound, solvodynamic shear forces cleave polymer chains into shorter fragments while maintaining the polymers chemical identity. Commercial polyacrylate-based PSAs are often accessed via petroleum-sourced monomers (Fig. Several environmental impact categories were examined, but particular attention was paid to the global warming potential (GWP) and cumulative energy demand (CED). First reported cases of SARS-CoV-2 sub-lineage B.1.617.2 in Brazil: an outbreak in a ship and alert for spread. SAP Certified with fifteen years of SAP development experience in UK and New Zealand. Applicants wishing to apply for more than one topic, must submit a separate proposal under each topic. Adoption is complex, emotional, life-altering. %PDF-1.7 5, 501516 (2020). produced all visualization. The Kick-off meeting of the LIFE-2021-SAP-NAT-NATURE TURTLENEST project will be held on January 20 in Rome, at the Legambiente headquarters. Google Scholar. Health 8, E1018E1026 (2020). LIFE-2022-SAP-NAT-GOV Gamtos valdysenos projektai (angl. 9, 407418 (2021). Tobing, S. D. & Klein, A. Molecular parameters and their relation to the adhesive performance of acrylic pressure-sensitive adhesives. Experimentally, a plateau is observed in the plot of weight-average molar mass (Mw) versus sonication time. Huang, C. et al. 10, 4153 (2021). However, for a given year, we can identify states with the largest reductions. The decline was larger for males, widening by 9.1% the femalemale gap in e0. The magnitude of the COVID-19 death toll was not homogenous across states and was associated with the pattern of spread18. To avoid inconsistencies between life tables estimated for 2019 and 2020, we applied the same methodology to 2019. USA 118, e2014746118 (2021). Our results quantify the effect of the COVID-19 death toll on life expectancy in Brazil. Usually, the mid-year population is a good approximation of person-years lived during the year. The G at each frequency describes an adhesives resistance to shear, and this term generally increases in samples with more chain entanglements (e.g., with increasing Mw). Lancet Glob. and M.T.R. As of 25 May 2021, 20 of the 27 capital cities have intensive care unit occupancy above 80% (half of those above 90%)20. Article life-2021-sap-nat nature-DcardPTT|202206| Also in May 2021, the first case of the Delta variant (B.1.617.2), first detected in India, was reported in Brazil26. Anyone you share the following link with will be able to read this content: Sorry, a shareable link is not currently available for this article. The authors thank Procter and Gamble (P&G) for supporting this work, as well as Ryan Hayes and Jonah Vilseck for assisting with simulations, Edwin Zishiri for assisting with synthesis, Gary Gilbertson, Bill Begley, and Yiping Sun for performing SEC on the PSAs, and Prof. Brian Love for his intellectual contributions. Creton, C. Pressure-sensitive adhesives: An introductory course. Liu, Y., Lotero, E. & Goodwin, J. G. Jr Effect of water on sulfuric acid catalyzed esterification. Closed-loop chemical recycling via depolymerization to monomer is also not currently feasible for these superabsorbent materials because side-chain degradation outcompetes depolymerization. Rochman, C. M. Microplastics research-from sink to source. Preparation of pressure sensitive adhesives from post-consumer superabsorbent polymers. & Brooks, C. L. Adaptive landscape flattening accelerates sampling of alchemical space in multisite dynamics. 1d). Report 19: the potential impact of the COVID-19 epidemic on HIV, TB and malaria in low- and middle-income countries. Instead, we envisioned a 23 step method from crosslinked sodium polyacrylate: (i) acid-catalyzed or base-mediated decrosslinking to generate linear polymers, (ii) optional sonication to lower the molar mass, and (iii) functionalizing via esterification to generate tack (Fig. https://www.fatersmart.com/ - (Accessed May 1, 2021). Peer review information Nature Medicine thanks Pedro Hallal, Usama Bilal and Vladimir Canudas Romo for their contribution to the peer review of this work. Expected Impact . The dataset provides the age and sex structure of hospitalized COVID-19 deaths, and frequent updates are made publicly available by the Ministry of Health (https://opendatasus.saude.gov.br/nl/dataset). Google Scholar. Buss, L. F. et al. Second, COVID-19 disrupted primary care services in Brazil27. Microwave-assisted hydrothermal decomposition of super absorbent polymers. https://www.ellenmacarthurfoundation.org/publications/the-new-plastics-economy-rethinking-the-future-of-plastics-catalysing-action (2017). We created data visualizations in R, ArcMap version 10.8 (ESRI) and Adobe Illustrator CS6. Three-quarters attack rate of SARS-CoV-2 in the Brazilian Amazon during a largely unmitigated epidemic. Chazovachii, P. T., Somers, M., Alfaro, J., McNeil, A. J. Manag. Presentation(edition Call 2021- content valid also for call 2022), European Climate Infrastructure and Environment Executive Agency, This site is managed by the European Climate, Infrastructure and Environment Executive Agency, LIFE-2022-SAP-NAT Nature and Biodiversity - Standard Action Projects (SAP), Follow the European Commission on social media, Programme for the Environment and Climate Action (LIFE), European Climate, Infrastructure and Environment Executive Agency, LIFE - Support for applicants (europa.eu). Also, the states with extreme values changed only for e65 for both sexes, with the lowest shifting from Roraima in 2019 to Amazonas in 2020. Dokumentai pareikjams: Gairs Paraikos forma (A ir B dalys) Priedas "Vietovs apraymas" Priedas "Ri ir buveini apraymas" Fifth, reductions in the health budget and changes in the health financing model are likely to affect health outcomes40. Previous studies used this approach to estimate life tables in the presence of COVID-19 (refs. X.iieS(,& BMJ Open 11, e042934 (2021). Next, we estimated total 2021 deaths, including COVID-19 confirmed deaths (\({\,}_nD_x^{COV}\)), reported by Brasil.io. We did not make any corrections for the under-registration of deaths. Primi bandi LIFE 2021-2027 - FIRST Because in-hospital COVID-19 deaths represent 89% of all COVID-19 deaths reported in 2021, we use them to proxy for the agesex distributions of all COVID-19 deaths. Across states, the largest declines were estimated for Amazonas (3.14 years), Amap (2.46 years) and Par (2.44 years). JAMA 324, 13911392 (2020). Hogan, A. et al. https://blogdoibre.fgv.br/posts/auxilio-emergencial-faz-pobreza-cair-em-plena-pandemia (2020). We quantified the effect of COVID-19 on reversing the progress in mortality reduction since 2000 (Methods). life 2021 sap nat nature - crownxmas.com Estimated change in e0 (c) and e65 (d) in 2021. 276, 123350 (2020). As expected, the VWs are higher with larger Mw, which is due to the increased chain entanglements. George Paulus Dias - Managing Director - GP3 - LinkedIn US Patent 9,321,868 B2 (April 26, 2016). Percentage loss due to COVID-19 mortality relative to increases in female and male e0 (a) and e65 (b) between 2000 and 2020 by state. Clean. Lpine, L. & Gilbert, R. Thermal degradation of polyacrylic acid in dilute aqueous solution. 1c), broadly mirroring the patterns across states (Fig. )fdg{ca8L[2!/5\r>yGFB]Jd0EH|-v6fmxtlv^{@-0x@oOXLx1)&f@4M6"S6,+I"zvM7AC ~z:Wy{wF3JkGZpd\ _] 7N8cPi} T.A. May 1998 - Jan 20012 years 9 months. In contrast, a common approach used in industry to convert acrylic acid into acrylate esters uses inexpensive alcohols as both the reagent and solvent39,40. These are some examples of deteriorating health conditions that not only will generate a higher demand for healthcare services but also might affect future mortality patterns. Silveira, M. F. et al. Hone, T. et al. Project Manager for Product Governance - ziprecruiter.com From these studies, we conclude that the quantitative esterification of the polymer results from the hydrophobic reaction environment created by the polymer backbone and the 2-ethylhexanol solvent. PubMed Central An alternative recycling route known as chemical recycling was developed to address these challenges8,9,10,11. Mandeep Pandey, E.I.T. - Graduate Student - LinkedIn For all intervals except ages 01, 15 and 90+, the interval length n is 5 years wide. Super absorbent polymer recycling to pressure sensitive adhesives. C.M.T. Process Saf. Similarly to Brazil, many other countries in Latin America experienced a relatively fast pace of mortality improvement during this period, benefitting from the public health and medical progress of their forerunners9,11. We demonstrate herein that our open-loop recycling approach to pressure-sensitive adhesives from superabsorbent polymers outcompetes the petroleum-derived syntheses on nearly every metric, including global warming potential and cumulative energy demand. Jul 13, 2021 Nature Governance ID:LIFE-2021-SAP-NAT-GOV Type of action: [object Object] Objective: To contribute to the protection of nature and biodiversityby: Supporting nature and biodiversity policy and legislation compliance assurance, and/or 916 (Springer International Publishing AG, 2018). The resulting materials exhibit low-to-medium storage and loss moduli, and as such, are applicable as general-purpose adhesives. Aburto, J. M. et al. Manaus, the capital of Amazonas, observed a very high attack rate after the first wave of the pandemic in 2020 (ref. For example, the 1918 influenza pandemic was estimated to have reduced e0 in the United States by 712 years7. x:y*$J*e,=x QHM`zeF i(ED'*V[Xzd;KOtI102e2P\vto\jQ| Z Article Applicants wishing to apply for more than one topic, must submit a separate proposal under each topic. et al. Genomics and epidemiology of the P.1 SARS-CoV-2 lineage in Manaus, Brazil. Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. Globally, there have been significant efforts towards recycling the components of diapers28. LIFE-2022-SAP-NAT Nature and Biodiversity - Standard Action Projects (SAP) Page contents Details Description Details Status Closed Publication date 17 May 2022 Opening date 17 May 2022 Deadline model Single-stage Deadline date 04 October 2022, 17:00 (CEST) Funding programme Programme for the Environment and Climate Action (LIFE) Department Ichiura, H., Nakaoka, H. & Konishi, T. Recycling disposable diaper waste pulp after dehydrating the superabsorbent polymer through oxidation using ozone. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. Kick-off meeting of the projet LIFE-2021-SAP-NAT-NATURE TURTLENEST J. In this approach, the VW for each PSA is constructed from the dynamic storage (G) and loss (G) moduli at representative bonding and debonding frequencies of 0.01 and 100Hz, respectively. ISSN 1078-8956 (print). and C.M.T. :X"."o:XKw$0/vvDvXK Projects focussing exclusively on governance are excluded from this Call topic and covered by the related Call topic LIFE-2021-SAP-NAT-GOV. For both DT20 and DT19, after estimating the ratio of non-COVID-19 deaths to all-cause deaths, we then used this ratio to estimate the counterfactual life tables in which COVID-19 was eliminated and COVID-19 was included, respectively. served as a sounding board throughout the project. Fundao Oswaldo Cruz. We also used these period life tables to calculate the femalemale gap in e0 and e65 (Supplementary Table 7); the difference between the highest and lowest state life expectancies; the loss due to COVID-19 relative to increases in e0 and e65 (by sex and state) over the past two decades (20002020) (Supplementary Tables 8 and 9); and the setback in life expectancy due to COVID-19 identified by the years when the life expectancies estimated for 2020 and 2021 were last observed (Supplementary Table 10). In contrast, when acetic acid was reacted with ethanol/water, the conversion was only 68%. Roberts, I. B 121, 36263635 (2017). Tbuas Abreviadas de Mortalidade por Sexo e Idade. volume27,pages 16291635 (2021)Cite this article. Funding & tenders - European Commission Article performed the life cycle assessments mentored by J.A. Integrated Projects (all subprogrammes): 19 October 2021 - Concept Note. Nat. Moreover, the life cycle assessments, which utilized soiled diapers as the starting point, demonstrated that these open-loop recycling methods outperform the conventional routes from petroleum-derived feedstocks on nearly every metric, including for the key LCA metrics of global warming potential and cumulative energy demand. To interrogate this hypothesis, we measured the percent esterification under different conditions. We hypothesized that we could potentially eliminate the need to remove water because both the polymer backbone and our alcohol solvent are hydrophobic. Aileen Camantigue - National Capital Region, Philippines - LinkedIn Programma LIFE 2021-2027: primi bandi - GreenHoMe (John Wiley & Sons, Inc., 2003). State acronyms by region: North: AC=Acre, AP=Amap, AM=Amazonas, PA=Par, RO=Rondnia, RR=Roraima and TO=Tocantins; Northeast: AL=Alagoas, BA=Bahia, CE=Cear, MA=Maranho, PB=Paraba, PE=Pernambuco, PI=Piau, RN=Rio Grande do Norte and SE=Sergipe; Center-West: DF=Distrito Federal, GO=Gois, MT=Mato Grosso and MS=Mato Grosso do Sul; Southeast: ES=Esprito Santo, MG=Minas Gerais; RJ=Rio de Janeiro and SP=So Paulo; South: PR=Paran, RS=Rio Grande do Sul and SC=Santa Catarina. For decades, mechanical recycling has been used to recover some value from waste polymers, although recycling rates are low2 and the material quality is often reduced. National Geographic - Don't miss any show 1)24,25,26. The South was the last region to be severely hit by COVID-19 in 2020 (ref. Google Scholar. 4, 28912897 (2013). All environmental data were gathered from experiments, literature, or the ecoinvent database (version 3.5)51, and implemented in SimaPro v. 9.0.0.4850, as described in detail within the Supporting Information (Supplementary Information pgs S36S41). 48, 21812190 (2015). D.I.C., M.I.J., and E.N.G.M. M.C.C. 7 years of experience in SAP GL-MDM, SAP MDG and SAP ECC (Cost Center, Profit Center & General Ledger). Given multiple AIG Prestige, AIG EVP Quest and Citi E-Thank You awards for exceeding process target and providing continued assistance to the team.<br><br>SKILLS <br> Experienced in Master Data . Manages sample collection and retention strategy. To date, most diaper recycling efforts14 have focused on the cellulosic components, which can be biodegraded, incinerated to generate steam, pyrolyzed, or fermented to generate bioethanol15. These records, aggregated at the state level, are publicly available by date on the website (https://brasil.io/covid19/). Here, we assumed that individuals who did not die of COVID-19 in the first 4 months of 2021 would be subject to the 2019 age group-specific and sex-specific mortality rates. LIFE-2022-SAP-NAT-NATURE Gamta ir biologin vairov (angl. Part B 52, 873896 (2013). Therefore, we estimated the provisional decline in life expectancy in 2021 thus far; this estimate is based on the DT19 method noted earlier but, in this case, adding confirmed 2021 COVID-19 deaths to the deaths expected among those who did not die of COVID-19, who are assumed to be subject to 2019 mortality rates for the remainder of 2021 (Supplementary Table 11). Considering the large COVID-19 death toll in Brazil, with marked regional inequalities, our goal was to quantify the loss in e0 and e65 in 2020 and in the first 4 months of 2021 due to the pandemic. Reaction conditions for base-mediated and acid-catalyzed decrosslinking reactions with LCA comparison. R. Soc. Mohammed Ahmed Al-Nahari - UGRP Deputy General, VP - NCGR - National M.C.C. endobj Chem. g;"a"E^X @; In the meantime, to ensure continued support, we are displaying the site without styles Bars, organized by major regions, show changes for the states. https://www.vitalstrategies.org/resources/excess-mortality-in-brazil-a-detailed-description-of-trends-in-mortality-during-the-covid-19-pandemic/ (2020). As with 2020, for both e0 and e65, the lowest declines in 2021 were concentrated in the Northeast, whereas the South, which had relatively smaller declines in 2020, is estimated to have a much greater loss in 2021. Decrosslinking has been reported using ozonolysis16, though not for the purposes of mechanical recycling. 5)49,50. Excitingly, a viable central region pressure-sensitive adhesive is accessible without any sonication. On. Estimates of period mortality rates require an estimate of the population exposed to the risk of dying. Excess mortality in Brazil: a detailed description of trends in mortality during the COVID-19 pandemic. Soc. Degrad. Briefly, nonamers of polyacrylic acid were used as a model system along withbutanol Comparison of the reaction free energies was made between the first esterification and the final esterification. What it lacks is leadership commitment to save lives. The lack of a coordinated, prompt and equitable response informed by science, as well as the promotion of disinformation, have been the hallmark of the current administration27. Height influenced biomass accumulation and hence C gain, where life forms . The LIFE programme is structured in two fields - Environment and Climate Action - and it contributes to these priorities through its four sub-programmes: Environment field: 1. of 2-ethylhexanol and H2SO4 as a catalyst (Fig. Lett. It is also the case that the difference in life expectancy between 2019 and 2020 could encompass secular changes unrelated to the pandemic. In summary, the death toll of COVID-19 in Brazil has been catastrophic. M.C.C. endobj https://www.futuremarketinsights.com/reports/super-absorbent-polymer-market (20152020). Clin. . and C.M.T. Picture: Matt Roberts/Getty Images. Life Cycle Assess. Baqui, P., Bica, I., Marra, V., Ercole, A. PubMed Central When closed-loop processes are unavailable, an alternative, known as open-loop chemical recycling can be utilized. In any recycling effort, it is essential that a life cycle assessment27 is performed to determine the energy and environmental costs. Commission has launched on 17 May 2022 the LIFE Programme Calls for proposals. The complex viscosity again dropped several orders of magnitude over 24h, at which point no further changes were observed, again suggesting that most crosslinks have been hydrolyzed (Supplementary Fig. As a result, estimated e0 in Brazil in the presence of COVID-19 reflects levels observed in 2014 (Supplementary Table 10). That is, the PSAs are soft enough to flow and wet a substrate at the bonding frequency, while hard enough to hold onto a substrate, and peel cleanly at the debonding frequency. Following multiple decrement life table methods previously used to measure the effect of COVID-19 on life expectancy8,16,17, we calculated two additional sets of estimates of life expectancy decline: (1) the difference between 2020 life expectancy estimated above and a scenario in which COVID-19 mortality has been eliminated from 2020 (DT20; Supplementary Tables 3 and 4 and Methods); and (2) the difference between 2019 life expectancy estimated from 2019 death records and a scenario in which 2019 all-cause mortality has been inflated to include COVID-19 mortality (DT19; Supplementary Tables 5 and 6 and Methods). Reduction in life expectancy in Brazil after COVID-19. In this study, we used data on reported total deaths in 2020 and in JanuaryApril 2021 to measure and compare the death toll across states. ISPRA Istituto Superiore per la Protezione e la Ricerca Ambientale Phillips, T. Covid eruption in Brazils largest state leaves health workers begging for help. Science 372, 821826 (2021). La Commissione europea ha pubblicato i primi bandi del programma LIFE 2021-2027 per l' ambiente, il clima e l' energia . Although some cities temporarily closed some businesses in response to the unprecedented COVID-19 surge in early 2021, no financial support was provided from January to March 2021. Recent technologies for treatment and recycling of used disposable baby diapers. Health 7, e1575e1583 (2019). Programma Life - Sottoprogramma Natura e biodiversit - Bando per 4). Semin. Advancing sustainable materials management: 2017 fact sheet. Andrasfay, T. & Goldman, N. Reductions in 2020 US life expectancy due to COVID-19 and the disproportionate impact on the Black and Latino populations. Woolf, S. H., Chapman, D. A., Sabo, R. T., Weinberger, D. M. & Hill, L. Excess deaths from COVID-19 and other causes, MarchApril 2020. Preprint at https://www.medrxiv.org/content/10.1101/2021.02.26.21252554v1 (2021). In a previous paper, we described the spatiotemporal patterns of the spread of COVID-19 cases and deaths in Brazil18. Reaction conditions and yields for acid-catalyzed esterification of poly(acrylic acid), acetic acid, and undecanoic acid. For example, high degrees of esterification were observed via 1H NMR spectroscopy when using only 5 equiv. We offer five reasons as to why. A more limited version of the basic income program was re-established in April 2021. Lancet 397, 220232 (2021). hypno youtube. https://doi.org/10.1038/s41467-021-24488-9, DOI: https://doi.org/10.1038/s41467-021-24488-9. For 2019 and 2020, our estimates include deaths from all causes registered in the Mortality Information System. Recent efforts to sidestep this degradation using microwaves and added radical initiators led to oligomeric products with 5060% decarboxylation19. Peter Bauer, Jonas Brugger, Martin Posch, Sven Drefahl, Matthew Wallace, Gunnar Andersson, Hctor Pifarr i Arolas, Enrique Acosta, Mikko Myrskyl, Ian F. Miller, Alexander D. Becker, C. Jessica E. Metcalf, Stefano Amore, Emanuela Puppo, Giuseppe Liotta, Ariel Pablos-Mndez, Simone Villa, Richard Alan Cash, Megan ODriscoll, Gabriel Ribeiro Dos Santos, Henrik Salje, Nature Medicine Reduction in life expectancy in Brazil after COVID-19 - Nature ADS https://doi.org/10.1038/s41591-021-01437-z, DOI: https://doi.org/10.1038/s41591-021-01437-z. <> Marques, N. P. et al. Governors in that region imposed the most rigorous measures of physical distancing, in direct opposition to recommendations from the President14. LIFE-2022-SAP-NAT-GOV Nature Governance Each project application under the call must address only one of these topics. Prajapat, A. L. & Gogate, P. R. Intensification of depolymerization of polyacrylic acid solution using different approaches based on ultrasound and solar irradiation with intensification studies. You can alreadyfind all information and documentation needed at theFunding & Tenders Portal, includingthe call text and application forms. ANDS is a $120M federally funded national infrastructure innovation project to exploit Australia's research data advantage. Unfortunately, most used diapers sit in landfills without substantial biodegradation, or are incinerated. LIFE-2021-SAP-NAT Nature & Biodiversity - Standard Action Projects (SAP) LIFE-2021-SAP-NAT-GOV Nature Governance 19 , 2021 Robbie Morphew - SAP ABAP Developer - SEAT CODE | LinkedIn LIFE-2021-SAP-NAT-NATURE Nature and Biodiversity SMART OUTCOME-BASED projects based on Specific, Measurable, Attainable, Relevant, and Time-Bound objectives for the implementation of EU Nature and Biodiversity legislation or Targets of the EU Biodiversity Strategy for 2030 2. Further information on research design is available in the Nature Research Reporting Summary linked to this article. and JavaScript. A facile and highly efficient strategy for esterification of poly(meth)acrylic acid with halogenated compounds at room temperature promoted by 1,1,3,3-tetramethylguanidine. J. Org. U.S. Patent 9,447,309 B2. In closed-loop chemical recycling, chemical transformations are used to cleave the polymer into its monomers (depolymerization), or to create a polymer with equivalent function12. To probe the role of both solvent and substrate hydrophobicity, we used two different substrates (acetic versus undecanoic acid) and solvents (ethanol versus 2-ethylhexanol). A. Lancet 394, 345356 (2019). M.C.C. Upgrading of postconsumer absorbent hygiene products for bioethanol production. 4b,c). In late April 2021, a parliamentary commission of inquiry was launched to investigate the governments handling of the pandemic response41. California, United States. c, Bivariate choropleth map of the estimated change in e0 and e65 in 2020 based on the difference from life tables calculated for 2019 and 2020 by state. Super absorbent polymer (SAP) marketGlobal industry analysis, size and forecast.